Pd/La Complex foranti-Selective Catalytic Asymmetric Nitroaldol Reactions
نویسندگان
چکیده
منابع مشابه
DFT study of the asymmetric nitroaldol (Henry) reaction catalyzed by a dinuclear Zn complex
We report the mechanism of asymmetric nitroaldol (Henry) reaction catalyzed by a dinuclear Zn complex using density functional theory. The experimentally proposed catalytic cycle is validated, in which the first step is the deprotonation of nitromethane by the ethyl anion of the catalyst, subsequently a C-C bond formation step, and then the protonation of the resulting alkoxide. Three mechanist...
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ژورنال
عنوان ژورنال: Synfacts
سال: 2008
ISSN: 1861-1958,1861-194X
DOI: 10.1055/s-2008-1077845